✦ LIBER ✦
Elektrochemische synthesen—XXI. Cyclovoltammetrische und epr-spektroskopische untersuchung des redoxverhaltens des [S4N5]−-ions
✍ Scribed by H.P. Fritz; R. Bruchhaus
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 342 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0013-4686
No coin nor oath required. For personal study only.
✦ Synopsis
Whilst the anodic oxidation of (Bu,N) t&N,] in 0,15 M (Bu,N) [BFa]/CHIC12 yielded no detectable radical species, the cathodic reduction at -40°C and at room temperature leads to epr spectra, which can be assigned to [S4N5]'-and [SN,] plus a species containing one N atom-possibly NS;.