Electrostatic potentials of strained systems: nitrocyclopropane

✍ Scribed by Peter Politzer; Linda N. Domelsmith; Per Sjöberg; Jack Alster

• Book ID: 103018387
• Publisher: Elsevier Science
• Year: 1982
• Tongue: English
• Weight: 409 KB
• Volume: 92
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(82)83430-1

✦ Synopsis

The prcscncc oi an NO2 subsrwcnt IS found IO chnnnxc the ncgatws clcctrostsrlc potcnttals assoaxted wth the "bent" C-C bonds m c) clopropsnc Thu IS presumably due tn large p.ut IO 3 rcxrangcmcnt of clcctromc chvge caused b) the mtro group. as IS ,ho!\n b) Llcctrontc dcnslt) chiicrencc plots Bond p3th ~lculat~ons rercal bent bonds tn tutrocycloprclpzmc that arc rcr) slmt1.u to thow III cyc1oprop.w.