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Electrostatic effect of chelation with metal ions on streaming potentials in chelating resins containing formazan derivatives

✍ Scribed by Tsutomu Watanabe; Kuniko Terajima; Masaaki Kubota; Akira Uchiumi


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
408 KB
Volume
276
Category
Article
ISSN
0003-2670

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✦ Synopsis


Electrostatic phenomena in chelating resins containing formazan derivatives were studied by measuring streaming potentials. It was found that the adsorption of metal ions can be related to the chelation due to proton replacement in the low pH region whereas it will be changed to adsorption due to electronegativity in the neutral pH region. The electrostatic potentials in the resin phase vary with metal chelation of the formazan groups. Metal chelation lowers the electrostatic energy, enhancing the stability of the resins.