Surface hydroxyl groups on metal oxides are sites for adsorption of cations or anions from water, which in turn release protons or hydroxide ions to solution resulting in ion-exchange reactions. It is important to know the mechanism of the formation of surface hydroxyl groups to understand the ion-e
✦ LIBER ✦
Electrostatic Cooperativity of Hydroxyl Groups at Metal Oxide Surfaces
✍ Scribed by Boily, Jean-François; Lins, Roberto D.
- Book ID
- 121467043
- Publisher
- American Chemical Society
- Year
- 2009
- Tongue
- English
- Weight
- 838 KB
- Volume
- 113
- Category
- Article
- ISSN
- 1932-7447
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Quantitative XPS has been used to determine the surface concentration of hydroxyl groups in native air-formed oxide Ðlms on metals having low surface areas. A mathematical expression has been derived to give the concentration of surface hydroxyl groups as a function of the intensity ratio of the OH