Electrospray mass spectra of medium-chain and long-chain acylcanitines
β Scribed by Barbara M. Kelly; Malcolu E. Rose; Darren Wycherley; Steven W. Preece
- Publisher
- John Wiley and Sons
- Year
- 1992
- Tongue
- English
- Weight
- 175 KB
- Volume
- 27
- Category
- Article
- ISSN
- 1076-5174
No coin nor oath required. For personal study only.
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The Wittig reaction between alkylidene triphenylphosphoranes [R CH = P(C6Hs)3, where R varied from H to n-C17H35] and methyl 12-oxooctadecanoate or methyl 10-oxohexadecanoate in dimethylformamide (DMF) has been employed in the synthesis of a partial homologous series of esters of branched chain fatt
Two sets of l-phenyl alkyl ester derivatives were synthesized from the acyl chlorides of medium-and long-chain fatty acids and l-phenyl-l-alkanols. The 'H-NMR analysis of these ester derivatives gave a characteristic signal at 5.73--5.89 6 for the methine proton (--COOCHPhR, where R = alkyl). The L3