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Electrosorption on heterogeneous surfaces—a statistical mechanical treatment

✍ Scribed by P. Nikitas

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
568 KB
Volume
33
Category
Article
ISSN
0013-4686

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✦ Synopsis

A statistical mechanical treatment for electrosorption of neutral organic compounds on heterogeneous surfaces is presented. A continuous-solvent model and a discrete-solvent one with and without lateral dip&r interactions are developed and discussed within the frame of lattice statistics and under mean field approximation. The adsorption isotherms obtained on the basis of the uniform distribution of the energy of sites may be considered as generalized Temkin isotherms.

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