✦ LIBER ✦

Electrosorption of neutral organic compounds from solvents of high dielectric constant. Triphenylphosphine oxide as a probe molecule

✍ Scribed by A.G. Anastopoulos

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 788 KB
Volume: 41
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(96)00067-9

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✦ Synopsis

The adsorption of triphenylphosphine oxide at the mercury electrode, from solvents of high dielectric constant, is studied by means of capacitance measurements against potential and time.

The usual interfacial parameters are determined and discussed. The calculated values of the Gibbs energy of maximum adsorption are found to be in satisfactory correlation with donor properties of the solvets used.