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Electrorheological properties of poly(o-anisidine) and poly(o-anisidine)-coated silica suspensions

✍ Scribed by Noriyuki Kuramoto; Yoshimi Takahashi; Katsutoshi Nagai; Kiyohito Koyama


Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
639 KB
Volume
30
Category
Article
ISSN
1381-5148

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✦ Synopsis


Poly(o-anisidine)

(PANS) and PANS-coated silica particles were prepared by oxidative polymerization of o-anisidine using ammonium persulphate in the absence and presence of silica particles, respectively. The entire surface of the silica particles was completely covered with PANS polymerized using low concentration of o-anisidine. The effects on the electrorheological behavior of surface modification of the silica particles coated with PANS were studied under oscillatory shear. Electrorheological properties of PANS and PANS-coated silica particle suspensions were found to exhibit higher performance in nonaqueous solutions than those of silica particle suspensions even at high temperatures.


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HCl-doped poly( o-anisidine) (PANIS-HCl) and undoped poly( o-anisidine) (PANIS-base) were blended with poly(2-methyl-2-oxazoline) (PMOx) or poly(2-ethyl-2-oxazoline) (PEOx) by solution casting from dimethyl sulfoxide. Blends containing 50 wt % or less of PANIS-HCl or PANIS-base were flexible and hom