Electrorheological properties of poly(o-anisidine) and poly(o-anisidine)-coated silica suspensions
β Scribed by Noriyuki Kuramoto; Yoshimi Takahashi; Katsutoshi Nagai; Kiyohito Koyama
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 639 KB
- Volume
- 30
- Category
- Article
- ISSN
- 1381-5148
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β¦ Synopsis
Poly(o-anisidine)
(PANS) and PANS-coated silica particles were prepared by oxidative polymerization of o-anisidine using ammonium persulphate in the absence and presence of silica particles, respectively. The entire surface of the silica particles was completely covered with PANS polymerized using low concentration of o-anisidine. The effects on the electrorheological behavior of surface modification of the silica particles coated with PANS were studied under oscillatory shear. Electrorheological properties of PANS and PANS-coated silica particle suspensions were found to exhibit higher performance in nonaqueous solutions than those of silica particle suspensions even at high temperatures.
π SIMILAR VOLUMES
HCl-doped poly( o-anisidine) (PANIS-HCl) and undoped poly( o-anisidine) (PANIS-base) were blended with poly(2-methyl-2-oxazoline) (PMOx) or poly(2-ethyl-2-oxazoline) (PEOx) by solution casting from dimethyl sulfoxide. Blends containing 50 wt % or less of PANIS-HCl or PANIS-base were flexible and hom