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Electroreductive Palladium-Catalyzed Ullmann Reactions in Ionic Liquids: Scope and Mechanism.

✍ Scribed by Laura Duran Pachon; Cornelis J. Elsevier; Gadi Rothenberg

Publisher
John Wiley and Sons
Year
2006
Weight
22 KB
Volume
37
Category
Article
ISSN
0931-7597

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## Abstract An efficient Ullmann‐type reductive homocoupling of aryl, vinyl and heteroaryl halides can be promoted by an aldehyde in tetraalkylammonium ionic liquids under very mild reaction conditions. This simple procedure generates symmetrical biaryls under relatively mild conditions. The ionic