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Electroreduction of Phthalazines and 1,2,5-Thiadiazoles: Structural Factors Determining the Opening of Heterocycle

✍ Scribed by N. V. Nastapova; V. V. Yanilkin; R. M. Eliseenkova; V. I. Morozov; E. I. Strunskaya; Z. A. Bredikhina; A. A. Bredikhin; B. I. Buzykin


Book ID
111608024
Publisher
SP MAIK Nauka/Interperiodica
Year
2003
Tongue
English
Weight
116 KB
Volume
39
Category
Article
ISSN
1023-1935

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3,4-Diphenyl-1,2,5-thiadiazole 1-oxide (1a) in acetonitrile solution is electroreduced to 2,4,6-triphenyl-1,3,5triazine and 3,4-diphenyl-1,2,5-thiadiazole. This behavior is very different from that of similar compounds with other oxidation states of the heterocyclic sulfur atom, such as the 1,1-diox