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Electroreduction of molecular oxygen on preferentially oriented platinum electrodes in acid solution

โœ Scribed by C. F. Zinola; A. M. Castro Luna; W. E. Triaca; A. J. Arvia


Publisher
Springer
Year
1994
Tongue
English
Weight
655 KB
Volume
24
Category
Article
ISSN
0021-891X

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๐Ÿ“œ SIMILAR VOLUMES


Temperature dependence of kinetic parame
โœ C.F. Zinola; A.M. Castro Luna; A.J. Arvia ๐Ÿ“‚ Article ๐Ÿ“… 1994 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 568 KB

The oxygen electroreduction reaction (OERR) kinetics at (111)-and (100)-type Pt electrodes has been studied in aqueous 1.0 M H2SO, solutions in the 8-62ยฐC range. On both Pt electrodes and at all temperatures, two Tafel regions have been observed. The Tafel slope in the low current density range is -

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The kinetics of oxygen reduction at Pt in trifluoromethanesulphonic acid (TFMSA) (0.05-6.0 M) and in 1.0 M TFMSA with addition of small concentrations of phosphoric acid (0.003-0.1 M) was investigated using the rrde technique. In TFMSA, the oxygen reduction current on the oxide-covered Pt was found