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Electrophylic metal-substitution in a tetradentate ligand and the catalytic effect of some anions.

✍ Scribed by Paola Gomez-Tagle; Lena Ruiz-Ramirez; Guillermo Mendoza-Diaz

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 69 KB
Volume: 51
Category: Article
ISSN: 0162-0134
DOI: 10.1016/0162-0134(93)85284-f

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## Abstract The catalytic mechanism of nitrate reduction by periplasmic nitrate reductases has been investigated using theoretical and computational means. We have found that the nitrate molecule binds to the active site with the Mo ion in the +6 oxidation state. Electron transfer to the active sit