Electrophilic α-Amination of Carbonyl Compounds
✍ Scribed by Ender Erdik
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 8 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
## Abstract The electrophilic amination constitutes an unconventional C−N bond‐forming reaction. Asymmetric versions have been developed using chiral reagents or catalysts and starting from optically pure substrates. The aminated products can be obtained with high stereoselectivities. These methodo
have recently been supplemented by selenophenol['] and transition metal hydrides[''. Reaction with typical hydride reagents such as LiAlH4i31, LiAl(OR)3H[31, and NaBH4i41 are usually sluggish. In this paper we wish to report that hydrogen telluride['] generated in situ has a high reducing ability t
## Abstract For Abstract see ChemInform Abstract in Full Text.