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Electrophilic Trifluoromethylation of S -Hydrogen Phosphorothioates

✍ Scribed by Santschi, Nico; Togni, Antonio

Book ID
127123686
Publisher
American Chemical Society
Year
2011
Tongue
English
Weight
984 KB
Volume
76
Category
Article
ISSN
0022-3263

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Trifluoromethyl sulfonium salts are widely used for the introduction of a trifluoromethyl group through reaction with a wide range of nucleophiles. Nevertheless, the reaction mechanism is far from obvious and has been the subject of various literature discussions. In this Letter, we show, through tr