𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Electrophilic Rearrangements of Chiral Amides: A Traceless Asymmetric α-Allylation

✍ Scribed by Peng, Bo; Geerdink, Danny; Maulide, Nuno


Book ID
121258847
Publisher
American Chemical Society
Year
2013
Tongue
English
Weight
816 KB
Volume
135
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


Asymmetric synthesis of α-amino acid der
✍ Nan Zheng; Joseph D. Armstrong III; J.Christopher McWilliams; R.P. Volante 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 218 KB

The utility of lithium t-butyl-N-tosyloxycarbamate (LiBTOC) as a ( + )NHBOC synthon in highly diastereoselective reactions with chiral cis-aminoindanol derived amide cuprates is described. The diastereoselectivities of these reactions ranged from 96% to greater than 99%. The subsequent transformatio