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Electrophilic Reactions of 2,4,6-Triphenylphosphabenzene

✍ Scribed by Priv.-Doz. Dr. G. Märkl; cand. chem. F. Lieb; cand. chem. A. Merz


Publisher
John Wiley and Sons
Year
1967
Tongue
English
Weight
216 KB
Volume
6
Category
Article
ISSN
0044-8249

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✦ Synopsis


Amidinium chlorides ( I ) condense with tetraphenylimidodiphosphinic trichloride chloride (2) 121 with elimination of 3 mol. equivalents of HCI when equimolar amounts are


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2,4,6-Triphenylphosphabenzene
✍ Dr. G. Märkl 📂 Article 📅 1966 🏛 John Wiley and Sons 🌐 English ⚖ 225 KB 👁 1 views

## 1,3-Diphenylbenzo[c]furan ( I ) has proved of particular value for the detection of lower-membered cycloalkynes [I]. In order to ascertain that it is cyclohexyne which is trapped, in accordance with equation (a), and not perhaps 1,2-cyclohexadiene, we have generated the cyclic allene by an inde