✦ LIBER ✦

Electrophilic benzylation and nitration of 2,6-dimethylanisole, 2,6-dimethylphenol and 2,6-diisopropylphenol. Isomer distribution and mechanistic considerations

✍ Scribed by Laali, Khosrow

Book ID: 127263208
Publisher: American Chemical Society
Year: 1985
Tongue: English
Weight: 437 KB
Volume: 50
Category: Article
ISSN: 0022-3263
DOI: 10.1021/jo00219a045

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reactions of 2,6-dimethylphenol and 2,6-

Reactions of 2,6-dimethylphenol and 2,6-dimethylanisole with electrophilic allylating agents

✍ Miller, Bernard; McLaughlin, Michael P. 📂 Article 📅 1982 🏛 American Chemical Society 🌐 English ⚖ 633 KB

Electhophilic allylation of 2,6-dimethyl

Electhophilic allylation of 2,6-dimethylphenol and 2,6-dimethylanisole at meta-positions

✍ Bernard Miller; Michael P. McLaughlin 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 143 KB

Electrophillc benzylations of 2,6-dimethylphenol and its ethers give surprisingly hia yields of products of attack at m&a-positions of the aromatic rings.1 Examination of possible mechanisms for meta-benzylation showed that only direct attack at the r&a-positions was consistent with sll the evidence

Aromatic sulfonation. 90. Sulfonation of

Aromatic sulfonation. 90. Sulfonation of three symmetrical 2,6-dialkylphenols, 2,6-dimethylanisole. Sulfation and sulfonation product distributions and mechanisms

✍ Cerfontain, Hans; Koeberg-Telder, Ankie; Lambrechts, Hans J. A.; De Wit, Peter 📂 Article 📅 1984 🏛 American Chemical Society 🌐 English ⚖ 822 KB

High percentages of substitution meta to

High percentages of substitution meta to oxygen in electrophilic benzylation of 2,6-dialkylphenols and aryl ethers

✍ Michael P. McLaughlin; Virginia Creedon; Bernard Miller 📂 Article 📅 1978 🏛 Elsevier Science 🌐 French ⚖ 289 KB

Hydmw and alkoxy groups on aromatic rings are powerful ortho-w directing substituents in -electrophlllc substitution reactions. We have confirmed, for instance, previous reports1 that Friedel-Crafts benzylatlcm of phenol, anisole, snd orthc-cresol gives solely products of substltution at positions o

Deuteration of closo-1,2- and 1,7-C2B10H

Deuteration of closo-1,2- and 1,7-C2B10H12 using C6D6/AlCl3: Mechanistic considerations

✍ Hans Lee; Thomas Onak; Jojo Jaballas; Uyen Tran 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 261 KB

Regioselective deuteration of 1-X-C 2 B 10 H 12 (X ‫ס‬ 2, 7) cage systems with C 6 D 6 /AlCl 3 is correlated to ab initio calculational results on a [C 2 B 10 H 13 ] ‫ם‬ intermediate. Full geometry optimizations of pertinent [C 2 B 10 H 13 ] ‫ם‬ isomers, derived from each of the two 1-X-C 2 B 10 H 1

Crystallographic data for the α and β is

Crystallographic data for the α and β isomers of 4-hydroxy-2,2,6-trimethylpiperidine hydrochloride and the β-O-benzyl hydrochloride

✍ Scane, J. G. 📂 Article 📅 1963 🏛 International Union of Crystallography 🌐 English ⚖ 111 KB