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Electrophilic behavior of tetracyanoethylene toward transition metal—carbon σ bonds. Reactions with 2-alkenyl and 2-alkynyl complexes

✍ Scribed by S.R. Su; A. Wojcicki


Book ID
114041237
Publisher
Elsevier Science
Year
1974
Tongue
English
Weight
603 KB
Volume
8
Category
Article
ISSN
0020-1693

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The reactions of q5-CsHs Fe(CO)2 CH,GCR (R = CH3, C&, and CH,Fe(CO)2($-CsHs)), $-C,Hs-Mo(CO), CH, CXC, H5, and Mn(CO)s CH, CWC, H5 ( [M] CH, ECR) with the ketenes (C6Hsjz C=C=O and (t-C4H9)(CN)C=CL-0 and with the N-sulfinyl compounds C, Hs N=S=O and p-CH3 C6H4S0, N= S=O result in the formation of (3