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Electrophilic alkynylation of ketones using hypervalent iodine

✍ Scribed by Utaka, Aline; Cavalcanti, Livia N.; Silva, Luiz F.


Book ID
121511362
Publisher
Royal Society of Chemistry
Year
2014
Tongue
English
Weight
675 KB
Volume
50
Category
Article
ISSN
1359-7345

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πŸ“œ SIMILAR VOLUMES


Hypervalent iodine oxidation of amines u
✍ Robert M Moriarty; Radhe K Vaid; Michael P Duncan; Masahito Ochiai; Minako Inena πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 French βš– 256 KB

Primary aliphatic amines on oxidation with iodosobenzene in CH2C12 or H20 yield the corresponding nitriles, while primary cycloalkylamines give the corresponding cyclic ketones. Lactams are obtained by the oxidation of cyclic amines. (S)(-) Nicotine (JJ,) is oxidized to (+)-cotinine (a). The interm