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Electrophilic additions to strained olefins

✍ Scribed by Traylor, Teddy G.

Book ID
121374099
Publisher
American Chemical Society
Year
1969
Tongue
English
Weight
886 KB
Volume
2
Category
Article
ISSN
0001-4842

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## Abstract 5,12:6,11‐Di[1,2]benzenodibenzo[a,e]cyclooctene (tetrade‐hydrodianthracene, TDDA) (1) reacts with halogens to give transannular (__anti__) 4, 5 and ring‐opened (__syn__) products 6, 7. The product ratio shows a remarkable solvent dependence. Solvents of medium polarity favor __anti__ ad