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Electrophilic addition of benzeneselenenyl chloride to hydroxyalkynes

โœ Scribed by Filer, Crist N.; Ahern, David; Fazio, Robert; Shelton, Emma J.

Book ID
120993300
Publisher
American Chemical Society
Year
1980
Tongue
English
Weight
453 KB
Volume
45
Category
Article
ISSN
0022-3263

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๐Ÿ“œ SIMILAR VOLUMES

Benzeneselenenyl p-toluenesulfonate: For
Benzeneselenenyl p-toluenesulfonate: Formation and electrophilic addition to acetylenes
โœ Thomas G Back; K Raman Muralidharan ๐Ÿ“‚ Article ๐Ÿ“… 1990 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 260 KB

The title compound 1 was produced in situ from PhSeCl and AgOSO+ (Ar= p-tolyl), and underwent electrophilic addition to acetylenes to afford adducts g. The same products were unexpectedly formed from the reaction of ArSOsH and AlBN, or from the pyrolysis of ArS(O)SO+r, in the presence of acetylenes