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Electron–nuclear double resonance (ENDOR) studies of neutral odd–alternate aromatic hydrocarbon free radicals formed by thermal dissociation

✍ Scribed by I. C. Lewis; L. S. Singer


Publisher
John Wiley and Sons
Year
1985
Tongue
English
Weight
486 KB
Volume
23
Category
Article
ISSN
0749-1581

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✦ Synopsis


Electron

-nuclear double resonance (ENDOR) spectra are presented for the odd-alternate aromatic hydrocarbon neutral radicals phenalenyl, ['Hs]phenylphenalenyl and for the benzo[c,dJpyrenyl and benz-[d,e]anthracenyl radicals formed by thermal dissociative processes in solution. Proton hyperhe coupling constants were determined from the ENDOR spectra and were shown to give an excellent linear correlation with McLachlan spin densities with Q= -26.5 G.