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Electronically excited reactive complexes in the anionic copolymerization of nonpolar monomers

✍ Scribed by K. K. Kalninsh; A. F. Podol’ski

Publisher
SP MAIK Nauka/Interperiodica
Year
2010
Tongue
English
Weight
307 KB
Volume
51
Category
Article
ISSN
0022-4766

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📜 SIMILAR VOLUMES

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Abstraet--Existing methods to determine reactivity ratios in copolymerizations are critically discussed; particular emphasis is placed on the difference between exact and approximate procedures. Among the latter, the "intersection" method (Mayo and Lewis) and the "linearization" method (Fineman and

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Styrene (M1) has been copolymerized with 0-, m-and p-halostyrenes (M2) at temperatures between 40 and ll0~C, using azoisobutyronitrile as initiator; the halostyrenes were labelled with 14C in the fl-position. The compositions of the copolymers were determined by liquid scintillation counting. ## Si