Electronic transmission in trans-bis(1,2-dioximato)cobalt(III) complexes with organic bases—deprotonation reaction
✍ Scribed by Yukio Yamano; Isao Masuda; Koichiro Shinra
- Book ID
- 118908569
- Publisher
- Elsevier Science
- Year
- 1971
- Weight
- 326 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0022-1902
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The electrochemistry of six-coordinated cobalt(II1) cobaloximatic salts is reported in acetonitrile containing 0.1 M tetrabutylammonium hexathtorophosphate as supporting electrolyte. The investigated compounds are represented as R[Co(GH),I,] where GH-is ethanedial dioximate or glyoximate and R = H+,
The kinetics of the reactions of manganese(II1) complexes of trans-cyclohexane-l,2-diamine-NNN'N'-tetraacetic acid (H4cydta) and 2,2'-bipyridyl (bpy) have been investigated in the acid ranges [H'] = 1.00 x M and [H'] = 0.10 -1.00 M, respectively, at different temperatures and at a constant ionic str