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Electronic structures of I2− and I4− ions in γ-irradiated rigid solutions

✍ Scribed by Tadamasa Shida; Yasufumi Takahashi; Hiroyuki Hatano; Masashi Imamura


Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
420 KB
Volume
33
Category
Article
ISSN
0009-2614

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✦ Synopsis


Radical-anions of iodke, bromine, and monoiodochloride are produced in r-irradiated amorphous solids at 77 K, and their electronic and ESR spectra measured. On limited wvming of the irradiated solution dimerizntion by tile reaction 1; 3 12 + 14 occurs to produce the same species ils reported by Fornier de Violet et al. The electronic structure of tile dimeric anion is discussed in comparison with the monomeric znion.


📜 SIMILAR VOLUMES


Studies on Radical Cations I. Molecular
✍ Thomas Bally; Edwin Haselbach; Zuzana Lanyiova; Peter Baertschi 📂 Article 📅 1978 🏛 John Wiley and Sons 🌐 German ⚖ 780 KB

## Abstract γ‐Irradiation of tris (methylidene)‐cyclopropane (‘[3]radialene’) **1** in a rigid electron scavenging matrix (butylchoride/i‐pentane, 1:1) at 77 K leads to formation of its molecular cation **1**^+^. Slight softening of the matrix by a temperature increase of 3–5 K results in formation