✦ LIBER ✦

Electronic structures and energy relaxation in low-lying triplet states of chlorobenzene in rigid matrices

✍ Scribed by Takeshi Takemura; Masahisa Fujita; Shin-ichi Nagaoka

Publisher: Elsevier Science
Year: 1986
Tongue: English
Weight: 348 KB
Volume: 130
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(86)80421-3

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✦ Synopsis

Electronic structures and energy relaxation processes have been studied in the low-lying triplet states of chlorobenzene in rtgid matrices at 77 K. Time-resolved phosphorescence So -T excitation spectra, phosphorescence spectra and their decays by S,-+T excitation have been measured. Analysis of the results confirms the '(no*) state lying close to the lowest '(rr,x*) state and supports the dual phosphorescence emission mechanism proposed previously.

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