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Electronic structure of triple-decker sandwich compounds with P5, P6, As5, and CnHn as middle rings

✍ Scribed by Jemmis, Eluvathingal D.; Reddy, A. Chandrasekhar.


Book ID
126093525
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
497 KB
Volume
7
Category
Article
ISSN
0276-7333

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Electronic structure and bonding studies
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## Abstract DFT and hybrid HF‐DFT studies of structure and bonding of CpMP~6~MCp triple‐decker sandwich complexes, ranging from 18–28 valence electrons (VE) with M = Sc, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, and W, show that the middle P~6~ ring complexes adopt symmetric planar (28 valence electron cou