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Electronic structure of the tetracyanoplatinate(II) anion

โœ Scribed by Marsh, Dana G.; Miller, Joel S.


Book ID
126922767
Publisher
American Chemical Society
Year
1976
Tongue
English
Weight
395 KB
Volume
15
Category
Article
ISSN
0020-1669

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The electronic structure of the disilavi
โœ Josef Kalcher; Alexander F. Sax ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 335 KB

The electronic structure of the disilavinylidene ( HZSi = Si) -anion is investigated with the MC SCF CI and CEPA methods. In addition to the doublet ground state ( 2B2) with an electron affinity of 1.65 eV, an excited state (4A") is found which is still stable by about 0.6 eV. 'A, 'A\* \*B\* K(3a1)\