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Electronic structure of the binuclear anions Cr2Cl93−and Mo2Cl93−

✍ Scribed by D. V. Korol'kov; Kh. Missner


Book ID
112363543
Publisher
Springer
Year
1975
Tongue
English
Weight
509 KB
Volume
9
Category
Article
ISSN
0040-5760

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✍ G. V. Khvorykh; S. I. Troyanov; A. I. Baranov; A. A. Serov 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 German ⚖ 88 KB 👁 1 views

An ampule reaction between Mo and PCl 5 at 200 °C yielded (PCl 4 ) 2 [Mo 2 Cl 10 ], the first ternary compound in Mo±P±Cl system. Single crystal X-ray diffraction gave a triclinic unit cell: a = 6.870(1), b = 8.892(2), c = 9.423(2) A Ê , α = 100.24(2), b = 95.55(2), c = 96.12(2)°(V = 559.3(2) A Ê 3