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Electronic structure of square-planar transition metal complexes. I. Tetrachloroplatinate(2-) and tetrachloropalladate(2-) ions

✍ Scribed by Messmer, R. P.; Interrante, L. V.; Johnson, K. H.


Book ID
126899814
Publisher
American Chemical Society
Year
1974
Tongue
English
Weight
940 KB
Volume
96
Category
Article
ISSN
0002-7863

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Electronic structure of transition-metal
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## Abstract A new parameterization for the first transition metal has been proposed in the framework of CNDO/2 method. We carried out CNDO/2 calculation of hexamine complexes [__M__(NH~3~)~6~]^2+^ and hexa‐aquo complexes [__M__(OH~2~)~6~]^2+^ in the high spin state where __M__ = Mn, Fe, Co, Ni, and