## Abstract The title compounds are the first examples of solventβfree oxide methanesulfonates of Mo, U, Re, and V.
Electronic structure of sos - a comparison with O3, SO2, and S3
β Scribed by R.O. Jones
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 387 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The energy surfaces of low-lying states of SOS have been calculated using the density functional formalism. In contrast to the results for 0,. SO, and S,, the ground state has a closed (ring) structure, with asos = 75". Together with other differences in this family of molecules, this can be understood in terms of trends in the single-particle eigenvalues.
π SIMILAR VOLUMES
## Abstract Pulsed laser photolysis of O~3~ in a large excess of N~2~ has been used to generate O(^3^__P__) atoms in the presence of OCS. By observing chemiluminescence from the small fraction of electronically excited SO~2~ formed in the reaction of SO with O~3~, rate constants of (1.7 Β± 0.2) Γ 10
Mixtures of Cl:!, CH4, and 0 2 were flash photolyzed a t room temperature and pressures of -60-760 Torr to produce CH3O2. The CH3O2 radicals decay by the second-order process (6) 2CH302products with k g = (3.7 f 0.3) X cm3/sec in good agreement with other studies. This value ignores any removal by s
The mechanism of H$O4 formation via the reaction steps, SO1 t O$SO "\*' 3-(SO,: H,O) +H,SO,, has been investigated at low temperature in an argon matrix. Photooxydation of SO2 mainly occurs through the SO\*: O3 pairs. Photolysis of a SOI-H20-0, mixture did not lead to the H,SO, molecule. The I : 1 H