Electronic structure of Re2Cl82−

✍ Scribed by Albert P. Mortola; Jules W. Moskowitz; Notker Rōsch; Charles D. Cowman; Harry B. Gray

• Book ID: 103014845
• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 501 KB
• Volume: 32
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85125-6

✦ Synopsis

The multiple suttedng Xcr method has been used tb calculate the ord&ng of both occupied a& ~~cc~pi~d one-electron energy states of ReaClg-. Single crystal polarized electkic spectra of [(nC&)4N] z[Re2C!ls] have been measured at 5 K. Principal band maxima are observed at i4 180 (z), 30 870 Izy), hnd 39 21% (z) cm-". The :' calculation, ohserved polarizatiqns, and a comparison of band positions in Rez CIiand RezBrz-siiggest the following transition as&giments for the foimer complex: $4180 cmL1, bzg6 --c bru6w; 30870 cm-' ,eg-c b@*; 39 215 cm-l , eufl --)I e ir*. g

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