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Electronic Structure of Neutral and Monoanionic Tris(benzene-1,2-dithiolato)metal Complexes of Molybdenum and Tungsten

✍ Scribed by Kapre, Ruta R.; Bothe, Eberhard; Weyhermüller, Thomas; DeBeer George, Serena; Wieghardt, Karl


Book ID
126135277
Publisher
American Chemical Society
Year
2007
Tongue
English
Weight
272 KB
Volume
46
Category
Article
ISSN
0020-1669

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## Abstract The mono‐electronic reduction of __tris__(benzene‐1,2‐dithiolato)Mo(VI) and W(VI) complexes (ML~3~: M = Mo, W; L = S~2~C~6~H^2−^~4~, S~2~C~6~H~3~CH^2−^~3~) to their anionic forms ML^−^~3~ by L(+)‐ascorbic acid (H~2~A) has been studied in tetrahydrofurane (THF):water and THF:methanol by