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Electronic structure of mixed-valence ions: ESCA and MO calculations on [.eta.5-C5H5Fe(CO)]2-.mu.-Ph2P(CH2)nPPh2m+, (n = 1, 2); (m = 0, 1)

✍ Scribed by Sherwood, David E.; Hall, Michael B.


Book ID
126197245
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
702 KB
Volume
17
Category
Article
ISSN
0020-1669

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Metallacrown ethers with trans-tetracarb
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Photolysis of the cis-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%}, (1, n= 3; 2, n= 4; 3, n= 5) metallacrown ethers in tetrahydrofuran under nitrogen gives moderate yields of the corresponding trans-Mo(CO) 4 {Ph 2 P(CH 2 CH 2 O) n CH 2 CH 2 PPh 2 -P,P%} (4, n =3; 5, n= 4; 6, n= 5) metallac