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Electronic structure of lithium amide

โœ Scribed by Kamakura, N.; Takeda, Y.; Saitoh, Y.; Yamagami, H.; Tsubota, M.; Paik, B.; Ichikawa, T.; Kojima, Y.; Muro, T.; Kato, Y.; Kinoshita, T.


Book ID
121470068
Publisher
The American Physical Society
Year
2011
Tongue
English
Weight
505 KB
Volume
83
Category
Article
ISSN
1098-0121

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Lithium bis(N,N-dimethyl-2-aminoethyl)amide (1 a) and lithium N-methyl-N- (3,6-diaza-3,6-dimethyl)heptylamide (2) are dimers in toluene, THF and in the crystalline state where they exhibit diamond-shaped Li 2 N 2 cores. Tetracoordination of lithium is achieved by intramolecular binding of the amine