## Abstract Some alkyl and aryl isonitriles, considered as CO analogue σ‐donor and π‐acceptor ligands in transition metal chemistry, were studied by means of HeI photoelectron spectroscopy and electron transmission spectroscopy, in order to evaluate their donor–acceptor properties from the measured
Electronic structure of donor groups by photoelectron spectroscopy: Thioderivatives of the carboxylate group
✍ Scribed by A. Flamini; E. Semprini; G. Condorelli
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 448 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0009-2614
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## Abstract High resolution He (Iα) and He (IIα) photoelectron spectra of cubane are reported. The assignments of the bands to different states of the cubane radical cation are made on the basis of __ab initio__ STO‐3G and MINDO/3 calculations, using geometries optimized within each treatment. The
## Abstract Average bond distances and bond angles in carboxylic esters with different substitution patterns have been derived by analyzing data from many crystal structures retrieved from the __Cambridge Structural Database__ (CSD). Conformation‐al preferences in the attachment of substituents are
## Abstract Average bond distances and bond angles as well as conformational preferences in the φ and ψ torsion angles of carboxylic amides with different substitution patterns have been derived by analyzing data from many crystal structures retrieved from the __Cambridge Structural Database__ (CSD