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Electronic structure, geometry, and energetics of carbanion and carbocation of [1.1]ferrocenophane: An INDO study

โœ Scribed by A. Waleh; M. L. Cher; G. H. Loew; U. T. Mueller-Westerhoff


Publisher
Springer
Year
1984
Tongue
English
Weight
576 KB
Volume
65
Category
Article
ISSN
1432-2234

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NMR studies of phosphonate carbanions: I
โœ G. A. Webb; M.-P. Simonnin; J. Seyden-Penne; T. Bottin-Strzalko ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 324 KB

C and "P NMR data are reported for a series of phosphonate carbanions. In comparison with related uncharged molecules, the values of 'J(PC) are rather large. This is discussed with the help of some INDOSCPT spin-spin coupling calculations, which reveal that while the positive contact term makes the