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Electronic structure and the unimolecular reactions of imine peroixde HNOO

✍ Scribed by Takayuki Fueno; Keiichi Yokoyama; Shin-ya Takane

Book ID
105076997
Publisher
Springer
Year
1992
Tongue
English
Weight
531 KB
Volume
82
Category
Article
ISSN
1432-2234

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πŸ“œ SIMILAR VOLUMES

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We compare two systematic approaches to the calculation of reaction Ε½ . rates in liquid solutions: the separable equilibrium solvation SES approximation and the Ε½ . equilibrium solvation path ESP approximation. These approaches are tested for two y q Ε½ . q X X q reactions, ClCH q NH Βͺ Cl q H CNH R1

The influence of imine structure, cataly
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Systematic variation of the substrate structure has shown that the most effective substrates for Cu(ch-salen)-catalyzed asymmetric enolate alkylation reactions carried out under phase-transfer conditions are the para-chlorophenyl imines of amino esters. The other reaction parameters (solvent and sti