Electronic Structure and Spectrum of the (TmF8)6− Cluster

✍ Scribed by F. Anisimov; R. Dagys

• Publisher: John Wiley and Sons
• Year: 1972
• Tongue: English
• Weight: 480 KB
• Volume: 53
• Category: Article
• ISSN: 0370-1972
• DOI: 10.1002/pssb.2220530108

✦ Synopsis

Abstract

The crystal field splitting and g values in SrF~2~:Tm^2+^ were calculated within the framework of the (TmF~8~)^6−^ cluster using the Heitler‐London method. Two sorts of numerical Hartree‐Fock functions for Tm^2+^ electrons were used in the calculations. It is shown, that a better agreement between the values calculated and observed may be obtained using more expanded radial functions of the Tm^2+^ electrons.