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Electronic structure and reactivity of propellanes : Photoelectron spectra of thia[4.4.3]propellanes

✍ Scribed by Michael C. Böhm; Rolf Gleiter


Publisher
Elsevier Science
Year
1979
Tongue
French
Weight
420 KB
Volume
35
Category
Article
ISSN
0040-4020

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Structure of [4.4.4]propellane and [4.4.
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## Abstract The crystal structures of [4.4.4]propellane (monoclinic, __a__=12.053, __b__=7.832, __c__=13.001 Å, β=104.89°, space group __C__2/__c__, __Z__=4) and [4.4.4]propellatriene (monoclinic, __a__=7.876, __b__=12.651, __c__=13.164 Å, β=122.81°, space group __P__2~1~/__c__,__Z__=4) have been d

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## Abstract Treatment of (+)‐sclareolide (**1**) with polyphosphoric acid or __Eaton'__s reagent furnished, besides the anticipated cyclopentenone (−)‐**12** and its isomer (−)‐**15**, two diastereoisomeric [4.3.3]propellanes (−)‐**13** and (−)‐**14**, which possess interesting woody‐ambery odors.

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