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Electronic structure and disorder in NaxCoO2 and SrRh2O4

✍ Scribed by D.J. Singh; G.B. Wilson-Short; D. Kasinathan; M. Suewattana; M. Fornari


Book ID
113913239
Publisher
Elsevier Science
Year
2007
Tongue
English
Weight
425 KB
Volume
9
Category
Article
ISSN
1293-2558

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3-SrRh204 , a novel high temperature phase, is prepared as black powder by solid state reaction of SrCO3 with Rh in air. The compound crystallises in the space group P63c, Z = 1, with a = 3.0626(2) A and c = 11.3996(7) A. The structure consists of CdI2-type layers of edge sharing RhO6 octahedra with