Electronic structure and crystal-field states in V2O3
β Scribed by Z. Ropka; R.J. Radwanski
- Book ID
- 108239125
- Publisher
- Elsevier Science
- Year
- 2006
- Tongue
- English
- Weight
- 102 KB
- Volume
- 378-380
- Category
- Article
- ISSN
- 0921-4526
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## Abstract V~2~O~5~ crystals doped with different impurities of the M^__n__+^ (__n__ = 1 to 6) type are investigated by the EPR method. It follows from the experiment that all the paramagnetic defects are connected with the impurities present in the crystals. The main paramagnetic centre in V~2~O~
The title compound has been synthesized and its structure refined by using powder diffraction data. The structure is orthorhombic, space group Immm, with cell constants \(a=7.1156(9), b=10.2863\) (18), \(c=6.5756\) (9) \(\AA\), and \(Z=4\). Two types of \(\mathrm{Nb}\) atoms are present in the struc