Electronic structure and chemical bonding in the intergrowth phase of MNb4O6(M = Ba, K)
β Scribed by V. P. Zhukov; V. G. Zubkov
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 1994
- Tongue
- English
- Weight
- 524 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0022-4766
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π SIMILAR VOLUMES
The intermetallic compounds Sr 11 Bi 10 , Ba 11 Bi 10 , and (Sr 5 Ba 6 )Sb 10 have been obtained from melts of mixtures of the elements. They crystallize in the tetragonal system, space group I4/mmm, Ho 11 Ge 10 structure type, tI84 Pearson symbol, Z β«Ψβ¬ 4, with cell parameters a β«Ψβ¬ 12.765(3), 13.2
Ba 3 Mo 18 O 28 , a reduced ternary molybdenum oxide in the series M n$ Mo 4nΨ2 O 6nΨ4 with n β«Ψβ¬ 4, is a cluster compound containing Mo 4nΨ2 O 8nΨ10 clusters with n β«Ψβ¬ 4 trans edge-sharing molybdenum octahedra. Crystals of the compound were investigated by high-resolution electron microscopy (HREM