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Electronic structure and chemical bonding in the intergrowth phase of MNb4O6(M = Ba, K)

✍ Scribed by V. P. Zhukov; V. G. Zubkov


Publisher
SP MAIK Nauka/Interperiodica
Year
1994
Tongue
English
Weight
524 KB
Volume
34
Category
Article
ISSN
0022-4766

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The intermetallic compounds Sr 11 Bi 10 , Ba 11 Bi 10 , and (Sr 5 Ba 6 )Sb 10 have been obtained from melts of mixtures of the elements. They crystallize in the tetragonal system, space group I4/mmm, Ho 11 Ge 10 structure type, tI84 Pearson symbol, Z ‫؍‬ 4, with cell parameters a ‫؍‬ 12.765(3), 13.2

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Ba 3 Mo 18 O 28 , a reduced ternary molybdenum oxide in the series M n$ Mo 4nΨ‰2 O 6nΨ‰4 with n ‫؍‬ 4, is a cluster compound containing Mo 4nΨ‰2 O 8nΨ‰10 clusters with n ‫؍‬ 4 trans edge-sharing molybdenum octahedra. Crystals of the compound were investigated by high-resolution electron microscopy (HREM