## Abstract The Οβionization energies of the diβtβbutylpolyacetylenes with two, three, four and five conjugated triple bonds have been determined by He (IΞ±) photoelectron spectroscopy. The assignment of the bands to the __Ξ __βstates of the corresponding radical cations follows from simple correlati
Electronic states of substituted haloacetylene and cyanoacetylene radical cations
β Scribed by Gerhard Bieri; Edgar Heilbronner; Volker Hornung; Else Kloster-Jensen; John P. Maier; Fritz Thommen; Wolfgang von Niessen
- Book ID
- 103663269
- Publisher
- Elsevier Science
- Year
- 1979
- Tongue
- English
- Weight
- 1012 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0301-0104
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π SIMILAR VOLUMES
The radical cations ofcis-and transdecalin have been studied in different synthetic zeolite matrices by EPR spectroscopy. The radical cations were produced by y-radiolysis at 77 K. The tirst experimental observation of both the electronic states (2Al : a(4H)=50 G and \*A$ a(4H)=29 G) of the cis-deca
Zinc(II) complexes of substituted tetraphenylporphyrins, Zn[T(X-P)P], where X = H, p-F, p-Cl, m-Cl, p-CH 3 O, and m-CH 3 O, have been synthesized and characterized. Peripheral substitution shows marked changes in the chemical shifts of the phenyl proton resonances and E 1/2 values of the redox coupl