✦ LIBER ✦

Electronic states and radiative transitions in LiAr

✍ Scribed by Jian-ping Gu; Gerhard Hirsch; Robert J. Buenker; Ioannis D. Petsalakis; Giannoula Theodorakopoulos; Ming-bao Huang

Publisher: Elsevier Science
Year: 1994
Tongue: English
Weight: 577 KB
Volume: 230
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(94)01198-2

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✦ Synopsis

Ab initio MRD-CI calculations have been carried out on the ground and the eight lowest excited electronic states of LiAr, correlating with excited Li atom states up to 3d *D. The ground (X *I;+ (2s) ) and 2 *Z+ (2~) electronic states are repulsive while the higher excited states show shallow Rydberg minima. Rates of radiative bound-bound and bound-free transitions have been also calculated.

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