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Electronic state of Au in Cs2Au2Cl6 at high pressure

✍ Scribed by J. Stanek; S.S. Hafner; H. Schulz


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
132 KB
Volume
76
Category
Article
ISSN
0375-9601

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P–T phase diagram and Au valence state o
✍ N. Kojima; N. Matsushita πŸ“‚ Article πŸ“… 2000 πŸ› Elsevier Science 🌐 English βš– 231 KB

M 2 [Au I X 2 ][Au III X 4 ] (M=K, Rb, Cs; X=Cl, Br, I) are perovskite-type gold mixed-valence complexes. In this review, we describe their structural P -T phase diagram, the pressure induced Au valence transition from the Au I, III state to the Au II one, which is coupled with a structural phase tr