✦ LIBER ✦
Electronic spectra of pyramidal dications, (CCH362+ and (CH)62+.
✍ Scribed by H. Hogeveen; P.W. Kwant; J. Postma; P.Th. van Duynen
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- French
- Weight
- 224 KB
- Volume
- 15
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
Interest is increasing in the preparation, chemistry, and unusual bonding properties of pyramidal carbonium ions, fascinating newcomers to the nonclassical group. l-8 Representatives of two possible types of these ions, (CH)5, _, 2+ + 1 and (CH)6 , 2, have already entered the recent literature. The parent (CH): ion has been the subject of a number of calculationsi and a methyl substituted derivative has been prepared. 2 Preparative work on several substituted home-3 and bishomo-(CH): cations4 has also been reported.