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Electronic spectra and a theoretical study of the quinolizinium cation and the bromoquinolizinium cations

✍ Scribed by Cyril Párkányi; Georgine M. Sanders; Marinus van Dijk; Prof. Dr. E. Havinga

Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
534 KB
Volume
100
Category
Article
ISSN
0165-0513

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✦ Synopsis

Abstract

The PPP (Pariser‐Parr‐Pople) method has been used to study the quinolizinium ion (1) and the four isomeric bromoquinolizinium ions (2–5). The results have been used to interpret their electronic absorption and emission (fluorescence, phosphorescence) spectra. Also, predictions concerning the chemical reactivity of these compounds have been made and compared with the available experimental data.

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