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Electronic properties of two isomeric charge transfer [2.2]paracyclophanes

✍ Scribed by D. Schweitzer; K.H. Hausser; V. Taglieber; H.A. Staab

Book ID
103662254
Publisher
Elsevier Science
Year
1976
Tongue
English
Weight
387 KB
Volume
14
Category
Article
ISSN
0301-0104

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## Abstract Treatment of perhydro[2.2]paracyclophane (1) with trifluoromethanesulfonic acid for 15 h at room temperature in dichloromethane results in a quantitative yield of stereoisomer 2, in which one of the bridgehead hydrogen atoms points towards the inside of the molecule (mono‐__endo__ isome