Electronic properties of Pr4Ni3O10±δ
✍ Scribed by J.M. Bassat; C. Allançon; P. Odier; J.P. Loup; M. Deus Carvalho; A. Wattiaux
- Book ID
- 104372708
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- English
- Weight
- 624 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0992-4361
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The crystal structures of Nd 4 M 3 O 10 (M ؍ Co, Ni) correspond to the n ؍ 3 members of the Ruddlesden+Popper series of A n؉1 B n O 3n؉1 . Rietveld-type analyses of high-resolution powder synchrotron X-ray and powder neutron di4raction (PND) data of Nd 4 Co 3 O 10؉ and Nd 4 Ni 3 O 10؊ reveal the
We have studied the stability of Pr 2 NiO 4؉ under pure oxygen 6ow by in situ measurement of its weight versus T. Above 8503C a fast oxidation is observed corresponding to the ex-solution of PrO y species and to the formation of metallic Pr 4 Ni 3 O 10؊x . This reaction is not reversible. The quanti